硅钼蓝分光光度法测定环境水样中的硅_于辉.pdfVIP

30 9 Vol.30 No.9 2 0 0 9 9 ACT A A RMA MENT ARII Sep. 2009 硅钼蓝分光光度法测定环境水样中的硅 于辉, 翟庆洲, 杨辉 ( , 130022) 　　:Si( Ⅳ) 与钼酸铵在盐酸浓度为0.050 mol ·L-1 时生成硅钼黄, 当盐酸浓度为1.48 mol ·L-1 时经抗坏血酸还原硅钼黄生成硅钼蓝, 其最大吸收波长位于346 nm, 观摩尔吸光系数 ε = 346 nm 4 -1 -1 -1 4.5×10 L ·mol ·cm , 硅( IV) 量在0.1～2.8 μg ·m L 范围内遵守比耳定律。考察了36 种常见 共存物质的影响。本法成功地用于环境水样中硅的测定, 获得了满意的结果。 　　:分析化学;硅( IV) ;分光光度法;硅钼蓝;钼酸铵;水样 　　:O611.4 :A :1000-1093( 2009) 09-1268-03 Spectrophotometric Determination of Silicon in Environmental Water Sample with Silicomolybdate Blue YU Hui, ZHAI Qing-hou, YANG Hui ( Research Center for Nanotechnology , Changchun University of Science and Technology , Chang chun 130022, Jilin, China) Abst ract :Silicon ( IV) reacts with ammonium molybdate to form silicomolybdate yellow at hydrochlo- -1 ric acid concentratio n of 0.050 mol ·L .Silicomolybdate yellow is reduced by ascorbic acid and forms -1 silicomolybdate blue at hydrochloric acid concentration of 1.48 mol ·L .The max im um absorption of 4 -1 -1 the complex exhibits at 346 nm and the molar absorptivity is ε =4.5×10 L ·mol ·cm . 346 nm Beer s law is obey ed over the range of 0.1 ～ 2.8 μg ·m L-1 of silicon ( IV ) .The eff ect of thirty-six common co-existing substances on the determined results of silicon ( IV) w a