金属配合物催化剂催化苯乙烯的聚合研究论文.docVIP

题目：金属配合物催化剂催化苯乙烯的聚合 研究 PAGE PAGE III 金属配合物催化剂催化苯乙烯的聚合研究 摘 要 新型催化剂是高分子聚合反应过程和新性能的高分子材料合成的关键，对新型催化剂的研究推动了聚合物科学的发展。目前工业上所主要使用的烯烃聚合催化剂是Ziegler-Natta催化体系和茂金属催化体系，近年来后过渡金属烯烃聚合催化剂迅速发展，其特点使烯烃聚合的范畴又扩大了。 本课题主要是在乙酰丙酮镍（Ni(acac)2）为主催化剂、甲基铝氧烷（MAO）为助催化剂组成的催化体系下，在甲苯溶剂中进行苯乙烯的聚合实验，并考察了聚合温度、Al/Ni摩尔比、单体浓度和聚合时间等因素对聚合反应的影响。结果表明，Ni(acac)2/MAO催化体系显示出很高的催化活性。采用傅里叶变换红外光谱、差示扫描量热法对聚合产物进行表征。 关键词：配合物 ；催化剂；苯乙烯；聚合 Polymerization of styrene catalyzed by metal complex catalyst Abstract The novel catalyst is the key factor for the polymerization and the synthesis of polymer with new performance. New catalysts promote the development of polymer science. Currently olefin polymerization catalyst is mainly Ziegler-Natta catalyst systems and metallocene catalytic systems. In recent years, development of the transition metal olefin polymerization catalyst is rapidly; its features expanded the scope of olefin polymer. The paper study the polymerization of styrene with nickel acetylacetonate (Ni(acac)2) in the presence of methylaluminoxane (MAO) at toluene. The effects of polymerization temperature, Al:Ni molar ratio, the monomer concentration and polymerization time on the polymerization reaction were studied. The results showed that Ni(acac)2/MAO catalyst systems show high catalytic activity for the polymerization of styrene. The structure of the obtained polystyrene was characterized using Fourier transform infrared spectroscopy and differential scanning calorimetry. Key Words: complex; catalyst; styrene; polymerization 目 录 TOC \o 1-3 \h \u 4340 1 绪论 1 27533 1.1聚苯乙烯的介绍 1 32484 1.1.1聚苯乙烯的发展历史和产业现状 1 20135 1.1.2聚苯乙烯的特点及应用 1 10362 1.2苯乙烯的聚合研究 2 19551 1.2.1苯乙烯的聚合机理 2 30907 1.2.2苯乙烯的聚合工艺 5 2442 1.3烯烃聚合催化剂 7 1158 1.3.1Ziegler-Natta催化剂 7 16457 1.3.2茂金属催化剂 7 10252 1.3.3后过渡金属催化剂 8 31759 1.4本课题主要研究内容、目的及意义 10 2261 2 实验部分 12 2053 2.1引言 12 6685 2.2试剂和表征仪器 12 29769 2.3苯乙烯