水性光固化聚氨酯制备及表征 论文.docVIP

PAGE PAGE III PAGE PAGE I 题目：水性光固化聚氨酯制备及表征 水性光固化聚氨酯制备及表征 摘要 为响应二十一世纪高效、节能、绿色和环保的时代主题，水性紫外光固化体系以其无毒性、无污染、无刺激性和安全生产等优点，在众多的固化体系中脱颖而出，是目前较为活跃的研究和开发领域。 本文以异佛尔酮二异氰酸酯（IPDI）、聚四氢呋喃醚二醇（PTEMG1000）、二羟甲基丙酸（DMPA）、丙烯酸羟乙酯（HEA）和三乙胺（TEA）为原料，通过三步法合成了亲水性优异，能进行紫外光固化的阴离子型水性聚氨酯丙烯酸酯（WPUA），并将其乳化制得水性PUA乳液。 研究了水性聚氨酯丙烯酸酯树脂及其乳液的合成。讨论了光引发剂的种类和用量、中和剂种类、中和度、固含量以及反应物配比对光固化速度的影响，同时对光固化膜的性能进行了测定，并讨论了亲水基团含量、中和度、固含量和异氰酸指数对乳液性能的影响。假设UV-WPU作为传感材料所做的一些测试。通过测试我们可以确定UV-WPU可以作为pH传感材料。 关键词：UV固化；水性乳液；聚氨酯丙烯酸羟乙酯；光引发剂；传感材料 UV Curable Waterborne Polyurethane Synthesis and Characterization Abstract In response to the 21st century high efficiency, energy saving, green and environmental protection, water-borne UV curable system stands out in numerous curing system, with non-toxic, non-polluting, without excitant and production safety advantages, which is relatively active research and development fields. This paper introduce that an excellent hydrophilic and ionic UV-curing water-borne polyurethane acrylates(WPUA) was synthesized through the three-step synthesis method, with to Isophorone diisocyanate(IPDI), Polytetramethylene ether glycol(PTEMG1000), dimethylol propionic acid(DMPA), hydroxyethyl acrylate(HEA) and thiethylamine(TEA),which was made the water-borne polyurethane acrylate emulsion. The water-borne polyurethane acrylate emulsion(WPUA),water-based polish oil and ink formulations were studied. Photoinitiators’ type and dosage, neutralizer’s type, neutralization degree ,solid content and the ratio of reactants were discussed on the speed of light curing, meanwhile the performance of light curing film was studied, and the content of hydrophilic groups, neutralization degree, solid content and the isocyanate index were discussed on the properties of emulsion. Sometests the hypothesis that UV-WPU as sensing materials do, through the test we can determine the UV-WPU pH can be used as sensing material. Key words: UV-curing; Water-borne; Polyurethane-acrylicresin; Photoinitiator; Sensing material