环境科学超声衍生萃取法对土壤中草灭平的分析.docVIP

环境科学超声衍生萃取法对土壤中草灭平的分析 目录 TOC \o 1-9 \h \z \u 目录 1 正文 1 文1：环境科学论文超声衍生萃取法对土壤中草灭平的分析 1 1 材料与方法 3 2 结果与分析 4 3 小结与讨论 6 文2：综合性大学环境科学论文 6 一、环境科学专业特点及影响因素 6 二、环境科学本科专业人才培养学分要求 7 三、典型高校环境科学本科专业课程学分设置之比较 8 四、结语 8 参考文摘引言： 9 原创性声明（模板） 10 文章致谢（模板） 10 正文 环境科学超声衍生萃取法对土壤中草灭平的分析 文1：环境科学论文超声衍生萃取法对土壤中草灭平的分析 Determination of Chloramben in Soil by Ultrasonic Assisted Extraction and Derivatization Method LI Ke， ZHANG Li， ZHAO Guo-xing (Ititute of Hydrogeology and Environmental Geology， Chinese Academy of Geological Sciences， Zhengding 050803， Hebei， China) Abstract： Chloramben as a bifunctional compound was studied. The carboxyl group reacted with basic complexing agent Na4-EDTA to form a complex compound， so that polar was reduced and extraction was simplified. Derivatization and extraction was acted under ultrasound with pentafluorbenzyl bromide(PFBbr) as derivatization reagent. In the complexation reaction， it was confirmed that Na4-EDTA had good complexing capacity when water was introduced. The complex had good stablity. Ultrasonic assisted extraction promoted the derivatization. Complexation and derivatization interacted each other. Calibration curve showed a good linearity in a the range of ～ μg/kg with correlation coefficients of detection limit was lower than μg/kg when negative ion chemical ionization(NCI-MS) was used. The spiked recoveries of different concentratio were 86%～103% with relative standard deviatio of 5%～10%. The method proposed could meet the determination of chloramben in samples of soil and plant。 Key words： complexation; ultrasonic assisted extraction-derivatization; soil; chloramben 草灭平是选择性芽前除草剂，使用较为广泛，由于其移动性较大，容易对水、土造成污染。在草灭平分子结构中，同时含有-COOH和-NH2，其强极性的特点使萃取难度增大，物理萃取方法难以取得好的效果。络合反应后化合物极性的降低可使萃取简单化[1]。目前，多数报道[2， 3]所采用的络合剂多是中性含磷络合剂和酸性含磷络合剂(含有P=O键)，如针对羧基或羟基使用的磷酸三丁酯(TBP)、三辛基氧膦(TOPO)和针对氨基使用的二(2-乙基己基)磷酸等。同加速溶剂萃取和索氏提取相比，超声萃取具有使用的溶剂量少、背景值低，相同时间内所萃取的样品多等优势[4， 5]，但目前的应用也只限于对化合物的萃取。本研究旨在在络合反应的基础上，建立一种集萃取、衍生于一体的技术路