物化上双语课件13-7.pptx

版权所有：华东理工大学物理化学教研室;版权所有：华东理工大学物理化学教研室;1.3 pVT Diagrams, Gas-Liquid Transition and Critical Phenomena 1.4 pVT Diagrams and Phase Diagrams with Solid Phase Included 1.5 Van der Waals Equation 1.6 Generalized Calculations and the Corresponding-State Principle 1.7 Virial Equation;6. Compressibility-Factor Chart; pVT State Diagrams with Gas, Liquid and Solid Phases Included;pVT Diagrams, Gas-Liquid Transition and Critical Phenomena;2. Phase Diagram;1.3 pVT Diagrams, Gas-Liquid Transition and Critical Phenomena 1.4 pVT Diagrams and Phase Diagrams with Solid Phase Included 1.5 Van der Waals Equation 1.6 Generalized Calculations and the Corresponding-State Principle 1.7 Virial Equation;;For ideal gases: 1). The size of molecules is negligible; 2). Molecules do not interact; …;2. The van der Waals equation;2. The van der Waals equation;2. The van der Waals equation; Several forms ;3. Application to Gas-Liquid Transition;Maxwell Rule;3. Application to Gas-Liquid Transition;4. Improvement of van der Waals Equation;1.3 pVT Diagrams, Gas-Liquid Transition and Critical Phenomena 1.4 pVT Diagrams and Phase Diagrams with Solid Phase Included 1.5 Van der Waals Equation 1.6 Generalized Calculations and the Corresponding-State Principle 1.7 Virial Equation;1. Applying van der Waals Equation to Critical Point;1). Reduced parameters;2. Generalized van der Waals Equation;3. Generalized Calculations of pVT Relations;3. Generalized Calculations of pVT Relations;4. Corresponding-State Principle;1.3 pVT Diagrams, Gas-Liquid Transition and Critical Phenomena 1.4 pVT Diagrams and Phase Diagrams with Solid Phase Included 1.5 Van der Waals Equation 1.6 Generalized Calculations and the Corresponding-State Principle 1.7 Virial Equation;1.7 Virial Equation;2). Virial coefficients;II. Thermal Properties ;Framework of the Chapter 1.1 Introduction 1.2 State and State Function