天津大学高等有机化学分子重排.pptxVIP

会计学;I Classification of Rearrangement Reactions ;第2页/共43页;Usually the rearrangement was classified by the electron property of the moving group, such as Nucleophilic rearrangement, Electrophilic rearrangement, Radical rearrangement, etc.;Electrophilic rearrangement;II Nucleophilic Rearrangement;第6页/共43页;Stable cation;第8页/共43页;第9页/共43页;2 Pinacolic Rearrangement;The stable cation formed superior;Phenyl with electron donor group move first;Under HNO2, the amino alcohol rearranges as that of pinacol ;3 α-Ethandione Rearrangement;第15页/共43页;α-Ethandione with α- hydrogen will proceed condensation