基于羧酸配体的金属有机配合物设计与组装.doc

PAGE 23 基于羧酸配体的金属有机配合物设计与组装 中文摘要 金属-有机骨架材料（MOFs）是以金属离子或金属簇作为连接点，以有机配体作为连接体构成的无限延伸的网络结构，在储能、催化以及分离等方面都起到了广泛的作用，可能充当分子识别、选择催化、超高纯度分离、光致变色、生物传导、光电等新型材料。由于金属-有机骨架材料（MOFs）具有结晶度高、纯度高、成本低，结构可控等一系列优点，它近些年来受到了全世界材料学研究者们的广泛关注。 本文采用水热法，利用4-(4-氧基-1-吡啶) 邻苯二甲酸(H2L)与Cd2+,采用水热法合成了两种金属-有机骨架配合物：CdL(H2O)2 (1)和CdL (2)，并对配合物1和2的结构进行了单晶X射线衍射表征。在配合物1和2中，配体L2-采用不同的配位方式，但是这两个配合物都是二维层状结构。粉末X射线衍射数据表明得到的配合物1是纯相样品。本文还对配合物1进行了紫外可见光谱和热稳定性测试。 关键词：金属-有机骨架，水热合成，含氮羧酸，晶体结构 Design and assembly of metal organic complexes based on carboxylic ligand ABSTRACT Metal-organic frameworks (MOFs) possess infinite extensive network in which metal ions or metal cluster act as nodes and organic ligands function as linkers, they play important roles in storing energy, catalyzing and separation and they may have potential applications in molecular recognition, selective catalysis, separation with ultra-high purity, photochromism, biology conduction and photoelectric field. Because MOFs have a serial of advantages such as high crystallinity, high purity, low cost and adjustable structures, they have drawn extensive attention by the researchers all over the world. In this paper, using 4-(4-oxypyridinium-1-yl)phthalic acid (H2L) and Cd2+, two MOFs formulated as CdL(H2O)2 (1) and CdL (2) have been synthesized hydrothermally. The two MOFs have been structurally characterized by single crystal X-ray diffraction. In complexes 1 and 2, L2- ligand adopts different coordination modes, but the two complexes are two dimensional (2D) layer structures. Powder X-ray diffraction data indicates the bulk sample of complex 1 is in pure phase. The UV-vis spectrum and thermally stability of complex 1 have also been measured. Key words：MOFs, hydrothermal synthesis, Carboxylic ligand containing N atom, crystal structure 目 录 TOC \o "1-3" \h \z \u 中文摘要 I ABSTRACT II 1 绪论 1 1.1 金属-有机骨架配合物的简介 1 1.2 金属-有机骨架配合物的分类 1 1.2.1 含氮杂环有机配体构筑MOFs 2 1.2.2 羧酸有机配体构筑MOFs 2 1.2.3 含氮杂环配体与羧酸有机配体构筑MOFs 2 1.2.4 含膦酸配体构筑MOFs 2