水污染的超临界二氧化碳-压气机工况下的混合物热力性质.pdfVIP

Supercritical CO2 with Water Contamination; Mixture Thermodynamic Properties at Compressor Conditions Prof. Yee Chiew , Warren Jueng, and Stephanie Plant Department of Chemical Engineering Rutgers University, NJ and Ashvin Hosangadi and Tim Weathers CRAFT Tech Pipersville, Pa The 7th International Supercritical CO2 Power Cycles February 21 – 24, 2022 San Antonio, TX, USA Motivation • Direct-fired cycles are partially closed-loop systems where CO2 is recycled and compressed after water is condensed out of the exhaust • Compressors in direct-fired cycles will likely be required to operate with CO2 contaminated with some level of water as the working fluid From White and Weiland (2018) • Water contamination will lead to droplet generation at all operating pressures of relevance and despite the CO2 being at supercritical conditions relative to its pure phase properties • Generation of water rich droplets at compressor inlet potentially has significant implications for erosion and blade damage for long term operation • Focus of our paper is on the development of accurate models for phase boundaries, density and enthalpy for supercritical CO2 contaminated with water that can be integrated into modeling tools Qian, Privat, and Jaubert (2013)