基础材料和有机材料 (11).pdfVIP

Crystal imperfection and Solid solution QUESTIONS 1. (a) Calculate the thermal defect concentration at 25℃and 1600℃, given that ΔGF and ΔGS of CaF2 are 2.8eV and 5.5eV, respectively. (b) If there is 10－6 YF3 added to the CaF2 crystal as impurity, explain which kind of point defects dominate at 1600℃, thermal point defects or impurity point defects. Solution： ＜ΔG , (a) As shown above, ΔGF S combined that with the formula of , , it can be concluded tha