基础材料和有机材料 (4).pdfVIP

2.2.2 The rules for writing of defect reaction equation (1) Positional relationship The ratios of the number of regular cation and anion lattice sites in crystalline compound is constant. but the total number of sites of each ion can change. For example, NaCl crystal, the ratio of regular Na+ and chlorine sites should be 1:1 regardless of the actual composition. Actually, when defects are formed, the number of atoms in the crystal will change. For example, if foreign atoms are added to the system, the number of atoms and crystal size will increase. On the con