铝电解固废处理过程中高盐高氟废水中氟的去除研究.pdf

• 60 • 轻金属 2020年第9期 •相关技术• 铝电解固废处理过程中高盐高氟废水中氟的去除研究 张延利 （中铝郑州有色金属研究院有限公司，河南郑州450041） 摘要:本丈皋用化学沉淀-混■凝沉淀飭方法 ，利用石灰乳、氯化铝对铝电解大修渣湿法处理产生餡离盐含氟废水进 行除氟处理 。研究结果表明，石灰沉淀法可有效去除高盐高氟废水中飭氟，可使氟离子浓度降低至19. 0 mg/L0 A1C13 -6H2O W加入有利于离盐离氣废水中氟餡去除，在n(A]/F)等于5.0时，上清液中氟离子浓度为2.7mg/L,其作用的 pH最隹值约为6. 5 ~7. 5 。化学沉淀-混凝沉淀法对铝电解大修渣•湿法处理后的高盐含氟废水中飽杂质离子具有较 好的协同处置效果，为高盐溶液的后续处理和高值化利用提供了更广阔的空间。 关键词：高盐高氣；氟飽去除;工业氧化岛 中图分类号 ：TF821 文献标识码 ：B 文章编号 ：1002-1752(2020)09-0060-03 DOI： 10.13662/j. cnki. qjs. 2020.09.013 Study on removal of fluorine from high - salt and high - fluorine wastewater in the solid waste treatment of aluminum reduction Zhang Yanli (Zhengzhou Non —ferrous Metals Research Institute Co., Ltd. of CHALCO, Zhengzhou 450041, China) Abstract：In this paper, th limemilk and aluminum chlorid ar used with th method of chemical precipitation and coagulation precipitation to remov fluorin from th high - salt and fluorin - containing wastewater produced by th wet treatment of aluminum spent lining. Th results show that th method of lim precipitation can effectively remov fluorin from th high - salt and high - fluorin wastewater, as a result of which th concentration of fluorin ion can b reduced to 19.0 mg/L. Th addition of A1C13 • 6H2O is helpful to removing fluorin from th high - salt and high - fluorin wastewater. When n ( Al/F) is equal to 5. 0, th concentration of fluorin ion in th supernatant is 2.7 mg/L, and th optimal pH valu is about 6.5 ~ 7.5. Th method of chemical precipitation and coagulation precipitation has a good synergistic treatment effect on th impurity ions in th high - salt and fluorin - contai­ ning wastewater after th we