W-O-W复乳微胶囊的研究.docVIP

W-O-W复乳微胶囊的研究 W/O/W复乳微胶囊的研究 摘 要 微胶囊是由天然或合成高分子(壁材)制成的微型容器，它既可以包封和保护 囊内的液滴、微粒或气体(芯材)，还可以改善芯材的使用性能。微胶囊的粒径通 常在 0.1,1000μm ，外壳的壁厚在 0.01,10μm范围内不等。微胶囊的外形多种多样， 多为球形。微胶囊相变材料(MCPCM )是一种含有相变材料的微小容器。微胶囊 技术日益引起人们的注目，目前微胶囊技术的应用领域已涉及到日用化工、食品、 农药、医疗卫生等方面。本实验采用物理化学法中溶剂挥发的方法，以聚苯乙烯为 胶囊壁材，对无机钙盐CaCl ??6H O进行包覆，制备微胶囊相变材料。探索溶剂挥发 2 2 法包覆无机盐相变材料的工艺条件，研究了后处理所用不同溶剂、不同芯材用量、 外水相中加入不同PVA用量和添加纳米SiO 对微胶囊相变材料性能的影响。对产物 2 进行了红外、电镜、DSC和热失重等的表征。研究结果表明成功的制备出了粒径较 小且分布均匀的微胶囊。纳米SiO 的添加增强了微胶囊的热稳定性和强度。相信在 2 不久的将来，随着对相变材料的进一步挖掘和开发，微胶囊这一技术的应用 前景将 更加广阔。 关键词:相变材料，微胶囊，六水氯化钙，表征 I W/O/W复乳微胶囊的研究 Abstract Microcapsule is a subminiature container which can be made by crude or man-made macromolecule material. It can envelop and protect the liquid or gas material and also improve the capability of core materials. The particle size of microsphere is often 0.1 ,1000μm, the size of shell is 0.01 ,10μm approximately. It is often a spherical container. Microencapsulated of phase change materials MicroPCMs is a sort of microsphere .The technique of the microcapsulation is developed by people increasingly and has been applied in fields of foodstuff, pesticide, medical treatment and so on. Microencapsulated phase change materials were achieved by solvent evaporation in this article, using polystyrene as capsule’s shell and inorganic salt CaCl ??6H O as 2 2 capsule’s core. The effect of treameatment with the use of different solvents ，different amounts of core material, different weights of PVA added to external water phase and addition of nano-SiO were studied. The microcapsule was characterized by IR 、DSC 、 2 TG and SEM. The microcapsules with small size and uniform distribution were prepared successfully. The addition of nano-SiO2 enhances the microencapsulation of thermal stability and strength. Key words: Microencapsule, Phase change material, Caloride chloride hexahydrade ， Characterization II W/O/W复乳微 胶囊的研究 目 录 第一章 前 言 ......................................................