化工分离过程7_2-1相平衡基础-1.pptVIP

The φ-φ approach is based on using an Equation of State (EOS). The fugacity of each component is determined by using an EOS. The same EOS describes both phases. The φ-φ approach is a powerful tool and it is relatively accurate if used appropriately. This approach is widely used in industry for light hydrocarbon and non-polar systems. φ-φ approach 状态方程法的关键 选择一个既适用于气相，又适用于液相的状态方程 状态方程 (Equation of State (EOS)) 关键在于选择合适的状态方程。对状态方程的选择不同以及同一状态方程的混合规则不同，逸度系数的具体表达式多种多样。 较常用的状态方程： RK方程、RKS方程、PR方程、PRS方程、BWRS方程 缺点：对状态方程要求较高，很多物系难以找到合适的状态方程。 优点：避免了活度系数基准态的确定。 Table 2.1 Useful Equations of State