毕业论文-固溶温度对2304双相不锈钢点蚀行为的影响.docVIP

PAGE 1 PAGE 1 固溶温度对2304双相不锈钢点蚀行为的影响 摘 要 双相不锈钢因兼具奥氏体和铁素体的优良特质而逐渐成为一种重要的结构材料。另外，这类不锈钢比工业上常用的奥氏体不锈钢更加节约镍资源，故而双相不锈钢逐渐在石化、冶金、造纸、原子能等各个工业领域得到了广泛应用。但是与其它种类双相不锈钢一样，各种热加工和焊接工艺都会使得这类双相不锈钢原有的稳态平衡被打破，并有其它二次相析出。这些都会使得这类合金易于在腐蚀介质中产生局部腐蚀。本文利用动电位极化曲线测试法和微观形貌观察法对不同固溶温度热处理后的UNS S32304双相不锈钢的点蚀行为进行仔细研究。研究结果表明，当样品的固溶热处理温度低于1080 ℃，样品的奥氏体相为弱相，在高于1080 ℃的条件下固溶，样品的铁素体相为弱相。1080 ℃为UNS S32304双相不锈钢的最佳固溶温度。 关键词: 双相不锈钢，固溶温度，耐点蚀性  Effect of Solution Temperature on UNS S32304 Duplex Stainless Steel Pitting Behavior ABSTRACT Duplex stainless steels have gradually become an important structure material due to their attractive combination of the better atributions of austenite and ferrite. On the other hand, duplex stainless steels are widely used in many fields, such as petrochemical industries, metallurgy, papermaking, nuclear power and so on due to their lower contents of nickel and molybdenum compared with austenite stainless steels which have been widely used in the industry. However, during hot work or welding, their phase balance is disturbed and some undesirable phases are prone to form. This makes the alloys prone to producing pitting corrosion in corrosive media. The thesis focuses on the effect of annealing temperature on the pitting corrosion behavior of UNS S32304 duplex stainless steel using morphological observation and the potentiodynamic polarization technique. The results demonstrated that when the specimens were annealed at the temperatures below 1080℃, austenite is the weak phase, and ferrite is the weak phase when the annealing temperatures increase over 1080 ℃. The best pitting corrosion resistance for this steel was found when annealed at approximately 1080 ℃. Keywords: stainless steel，the solution temperature，pitting resistance 0 引言 二十世纪70年代以来双相不锈钢作为耐局部腐蚀的结构材料，其开发与应用极为迅速，不论作为耐中性氯离子的应力腐蚀材料，耐氯化物的孔蚀与缝隙腐蚀材料或是耐甲铵液等的腐蚀疲劳材料，还是在别的许多方面，双相不锈钢凭借着其兼有铁素体不锈钢和奥氏体不锈钢的优点，已取代了AISI304L、316L、317L，甚至取代了904L等奥氏体不锈钢。随着化工工业的发展， 近年来双相不锈钢应用越来越广泛，尤其在石油、天然气、化肥、造纸及食品设备等行业有很大