毕业论文-时效温度对2404双相不锈钢点蚀行为的影响.docVIP

PAGE PAGE 45 时效温度对2404双相不锈钢点蚀行为的影响 摘 要 近年来由于镍和钼价格的上涨，节约型双相不锈钢在生产和应用过程中备受关注。为了使得节约型双相不锈钢在工业生产中获得更大的应用空间，一种新型节约型双相不锈钢2404双相不锈钢于2010首次被奥特昆普钢铁公司开发出来并在2011年获得了美国材料实验协会的许可。但是与其它种类双相不锈钢一样，各种热加工和焊接工艺都会使得这类双相不锈钢原有的稳态平衡被打破，并有其它二次相析出。这些都会使得这类合金易于在腐蚀介质中产生局部腐蚀。本文利用恒电位临界点蚀温度测试法和微观形貌观察法对中温时效热处理后2404双相不锈钢的点蚀行为进行仔细研究。研究结果表明，当样品的时效温度低于850℃，随时效温度的升高样品的点蚀抗力下降。之后，随温的进一步升高，样品的点蚀抗力上升。850℃为2404双相不锈钢点蚀抗力的最低时效温度。 关键词：双相不锈钢,点蚀,腐蚀机制,电化学测试  Effects of aging temperature on 2404 duplex stainless steel pitting behavior ABSTRACT In recent years, due to rising nickel and molybdenum prices, lean duplex stainless steel has got attention in the production and application process. To make saving duplex stainless steel for greater use of space in industrial production, a new lean duplex stainless -2404 duplex stainless steel was developed in 2010 for the first time by Outokumpu steel company and became available from the American Society for Testing and Materials (ASTM) in April 2011. However, during hot work or welding, their phase balance is disturbed and some undesirable phases are prone to form. This makes the alloys prone to producing pitting corrosion in corrosive media. The thesis focuses on the effect of aging temperature on the pitting corrosion behavior of 2404 duplex stainless steel using morphological observation and the potentiostatic critical pitting temperature technique. The results demonstrated that when the specimens were aged at the temperatures below 850℃, the pitting corrosion resistance decreased with the increase of temperature. After that temperature, the pitting corrosion resistance increase again with the increase of temperature. The lower pitting corrosion resistance for this steel was found when aged at approximately 850℃. Key words: Duplex stainless steel，Pitting Corrosion，corrosion mechanism，electrochemical measurement 目 录 TOC \o 1-3 \h \z \u 摘要 1 ABSTRACT 2 0 引 言 4