精对苯二甲酸生产技术及工艺流程.pdf

精对苯二甲酸(PTA)生产技术及工艺流程 摘 要 精对苯二甲酸〔PTA〕 英文名称：Pure terephthalic acid 〔PTA) 分子 式 C6H4 〔COOH 〕2 。 是以对二甲苯为原料，液相氧化生成粗对苯二甲酸， 再经加氢精制，结晶，别离，枯燥，得到精对苯二甲酸。精对苯二甲酸为 白色针状结晶或粉末，约在 300℃升华，自燃点 680℃。能溶于热乙醇，微溶 于水，不溶于乙醚、冰醋酸和氯仿。低毒，易燃。其粉尘与空气形成爆炸性混 合物，爆炸极限 0.05g/L～12.5g/ L。 精对苯二甲酸是生产聚酯切片、长短涤纶纤维等化纤产品和其它重要化工 产品的原料。精对苯二甲酸〔PTA〕是重要的大宗有机原料之一，其主要用途是 生产聚酯纤维 (涤纶)、聚酯薄膜和聚酯瓶，广泛用于与化学纤维、轻工、电子、 建筑等国民经济的各个方面，与人民生活水平的上下密切相关。 关键词：氧化反响 结晶 高压吸收 常压吸收 别离 枯燥 溶剂及催化剂 回收 残渣蒸发 溶剂脱水 萃取 常压汽提系统 加氢反响 过滤 可修改 欢送下载 精品 Word 目 录 要 · ······························· ································ ································ ·········· I 前 言 · ······························· ································ ································ ······ - 1 - 第一章精对苯二甲酸的工业概貌 · ······························· ································ - 2 - 1.1 世界精对苯二甲酸工业概貌 · ······························· ·························· - 2 - 1.2 我国精对苯二甲酸工业概貌 · ······························· ·························· - 3 - 第二章 精对苯二甲酸的上下游产业链································ ······················ - 5 - 2.1 精对苯二甲酸的上游产业································ ······························ - 5 - 2.2 精对苯二甲酸的下游产业································ ······························ - 5 - 第三章 精对苯二甲酸的性质及其主要用途 ································ ··············· - 6 - 3.1 精对苯二甲酸的性质 · ······························· ································ ···· - 6 - 3.1 精对苯二甲酸的主要用途································ ······························ - 6 - 第四章 精对苯二甲酸的主要原料································ ····························· - 7 - 第五章 产品方案及规格································ ································ ··········· - 8 - 5.1 产品方案································ ································ ······················ - 8 - 5.2 主