(6370)--感温变色建筑涂料的制备及光谱反射性能实验研究.pdfVIP

感温变色建筑涂料的制备及光谱反射性能实验研究 摘要：感温变色建筑涂料在降低建筑冷热负荷、改善城市热环境方面具有很大的应用潜力。为了探究感温变色 材料光学性能的影响因素，优化材料配方，首先制备了12种不同配方，变色温度为31℃的感温变色涂料，并分 析了金红石型TiO2质量百分含量对涂料光谱反射率和太阳光反射比的影响，研究表明涂料光谱反射率均随着TiO2 含量的增加而提高，感温变色粉最佳质量分数5%，TiO 的最佳质量分数应在5%~10%之间，此时浅色态的反射 2 比比深色态高0.2以上。同时探究了TiO2粒径对涂料在不同波段反射率的影响，结果表明，在紫外和除红光外的 可见光波段，感温变色涂料的反射率基本上随TiO2粒径的增大而减小；在红光和近红外波段，感温变色涂料反 射率基本上随TiO2粒径的增大而增大。 Developmentandspectralreflectanceanalysisofthermochromic coatingsforbuildings ZHANGYuxuan,ZHAIXiaoqiang (InstituteofRefrigerationandCryogenics,ShanghaiJiaoTongUniversity,Shanghai200240,China) Abstract:Thermochromiccoatingshavegreatapplicationpotentialinreducingthebuilding’sheatingandcooling load and improving the urban thermalenvironment.In orderto investigate the factorsinfluencing the optical propertiesofthermochromiccoatingsandoptimizethematerialformulation,12differentthermochromiccoatings withthecolor-changingtemperatureof31°Cwerepreparedbyincorporatingthermochromicpowderwithother assistantcomponents.TheeffectsofrutileTiO2 contentonthespectralreflectanceofthecoatingswereanalyzed. TheresultsshowthatthespectralreflectanceofcoatingsincreaseswiththecontentofTiO2.Theoptimummass fractionforthermochromicpowderis 5%,andforTiO2 isabout5%—10%,inwhichthesolarreflectanceof colorlessphaseishigherthanthatofcoloredphasebymorethan0.2.Atthesametime,theeffectsoftheparticle sizeofTiO2 onthereflectivityofthecoatingsindifferentbandswereinvestigated.Theresultsshowthatthe reflectivityofthethermochromiccoatingsdecreaseswiththeincreaseofTiO2 particlesizeinultravioletandvisible lightbandsexceptredband.Intheredandnear-infraredbands,thereflectivityofthethermochromiccoatings increaseswiththeincreaseofTiO2particlesize. Keywords:thermochromiccoatings;spectralreflectance;solarenergy;buildingenergysaving · ·3538