(6362)--微胶囊型自修复砂浆的制备及其性能优化.pdfVIP

微胶囊型自修复砂浆的制备及其性能优化 摘 要： 制备了具有裂缝自修复功能的微胶囊型自修复砂浆。其中，微胶囊以水溶性聚合物A 为壁材，以物理膨胀组分B 、溶胀 性聚合物C、混凝土膨胀剂D 和化学性膨胀组分E 为芯材，采用喷雾滚动造粒的方式制备而成。研究了微胶囊掺量和粒径分布对 微胶囊基本力学性能的影响，通过正交试验揭示了微胶囊芯材组分对砂浆自修复效果的影响并确定了微胶囊芯材的最佳组成。 研究结果表明随着微胶囊掺量的增加，自修复砂浆的抗压强度降低，当微胶囊掺量为20% ，选用粒径分布为0.15~4.75 mm 时，自 修复砂浆的抗压强度下降相对较少且微胶囊产率较高。微胶囊芯材中组分B 和组分D 的掺量是影响砂浆自修复性能的主要因 素，最终通过正交试验确定微胶囊芯材最佳组成为组分B ：25% ，组分C ：4% ，组分D ：20% ，组分E ：51%。 关键词： 自修复；微胶囊；制备；砂浆；性能优化 中图分类号： TU528.01 文献标志码： A 文章编号： 1002-3550 （2019）03-0124-06 JIN Haidong ，YANG Yang ，GU Chunping ，JIN Chengyang （College of Civil Engineering and Architecture ，Zhejiang University of Technology，Hangzhou 310012 ，China） Ab stract:Self-healing mortar，whose cracks can be self-healed ，was prepared with microcapsules.The microcapsules was with a round pot granulation method ，using water soluble polymer A as wall material and physical expansive component B ，swelling polymer component C ，concrete expansion agent D and chemical expansive component E as core materials.The influences of content and particle size of microcapsules on the mechanical properties of self-healing mortar were studied.The effect of core materials constitute in microcapsule on the self-healing efficiency of mortar were revealed with an orthogonal experimental program ，and the optimized constitute of core materials in microcapsules was determined.The results showed that the compressive strength of self-healing mortar decreased with the increasing of microcapsule content.When the microcapsule content was 20% ，and the particle size was in the range of 0.15~4.75 mm ， the reduction of compressive strength of mortar was relatively low.The dosages of physical expansive component B and concrete expansion agent D in the core materials of microcapsules are the main factors influencing healing efficiency of seal-healing mortar.With