(6515)--改性硫氧镁水泥耐水性及孔结构研究.pdf

改性硫氧镁水泥耐水性及 孔结构研究 　　摘　要 ：为了研究改性硫氧镁水泥的耐水性能和孔结构，对不同配合比水泥试件在常温下的孔结构及浸 水前后的抗压强度进行试验，并使用X- 射线衍射（XRD ）分析改性硫氧镁水化产物浸水前后的变化。试验 结果表明，掺入柠檬酸能提高硬化水泥石中孔孔含量，细化孔径提高MgO ∶MgSO4 的摩尔比、掺入柠檬酸 或粉煤灰能降低孔隙率。 　　关键词：改性硫氧镁水泥；外加剂；粉煤灰；耐水性能；孔结构 中图分类号：TU 525; TB 334 文献标志码：A 文章编号：1000 4726(2020)03 0374 04 　　 - - - study on wateR ResIstance and PoRe stRuctuRe of modIfIed magnesIum oxysulfate cement LI Zhen-guo, ZHENG Qi-shui, LIU Bo, ZHANG Xian-sheng, GUO Yang-yang, JIANG Li-li (College of Civil Engineering and Architecture, Harbin University of Science and Technology, 150080, Harbin, China) abstract: In order to study the water resistance and pore structure of modified magnesium oxysulfate cement, the pore structure and compressive strength of cement samples with different ratios were tested at normal atmospheric temperature before and after soaking. The changes of hydration products of modified magnesium oxysulfate cement were analyzed by X-ray diffraction (XRD). The results show that citric acid could increase the content of mesoporous pores. The porosity could be reduced by increasing the molar ratio of MgO MgSO , and water consumption, adding of citric acid or ∶ 4 fly ash. keywords: modified magnesium oxysulfate cement; additives; fly ash; water resistance property; pore structure 硫氧镁水泥是由MgSO4 溶液作为调和剂，与轻 和孔径大小等孔结构特征对水泥的耐水性能影响很