(6513)--改性石英岩粉对水泥浆体抗硫酸盐侵蚀的影响.pdfVIP

改性石英岩粉对水泥浆体抗硫酸盐侵蚀的影响　 摘　要　将掺未改性石英岩粉与改性石英岩粉的水泥浆体浸泡在40 ℃，5% Na SO 溶液中养护，测试改性石英岩粉对水泥浆体的膨胀率和 2 4 表面裂纹变化的影响，采用X 射线衍射仪(XRD) 和扫描电子显微镜(SEM) 对在Na SO 溶液中浸泡7 周的水泥浆体的侵蚀产物物相和微观结构 2 4 进行分析。结果表明：石英岩粉的掺入会明显加快水泥浆体的硫酸盐侵蚀膨胀和表面裂纹的形成，其主要原因是石英岩粉与水泥浆体疏松多孔的 微界面结构为外部SO 2- 的扩散提供了更多的通道，从而加快了水泥浆体的硫酸盐侵蚀。而改性石英岩粉与水泥浆体的微界面结构较为致密，阻 4 止了外部SO 2- 的侵入，从而抑制了水泥浆体的膨胀和裂纹的形成。 4 关键词　硫酸盐侵蚀；石英岩粉；微界面；膨胀；裂纹 TU528 　 A　　 1000-8098(2019)04 0016 04 中图分类号： 文献标识码： 文章编号： - - Influence of Modified Quartzite Powders on the Sulfate Attack Resistance of Cement Pastes Chen Deng1* Song Xuyan1 Wang Aiguo2 He Zhihai3 (1 College of Civil Engineering, Suzhou University of Science and Technology, Suzhou, Jiangsu 215011; 2 Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei, Anhui 230022; 3 College of Civil Engineering, Shaoxing University, Shaoxing, Zhejiang 312000) Abstract The cement pastes, prepared with equal contents of unmodified or modified quartzite powders, were immersed in 40 ℃ , 5% Na SO 2 4 solutions. The effects of the modified quartzite powders on the expansion and surface cracks of cement pastes were investigated. The phase composition of the products and the microstructures of the cement pastes immersed in the Na SO solutions at 7 weeks were analyzed using X-ray diffraction (XRD)