聚氨酯聚异氰酸酯固化剂安全拜耳提供中文.pptVIP

当前第30页\共有30页\编于星期三\10点 问候/自我介绍/内容介绍 注意语速/注意听众反应/时间控制 典型的双组份聚氨酯涂料－简单回顾 基料－作用成分/硬化剂－作用成分. Polyurethane coatings are reactive systems. The high molecular weight coating is formed directly on the substrate by cross linking of polyisocyanate and polyol component. Most of the Desmodur products used as coating raw materials are polyisocyanates of high molecular weight produced by polyaddition or polymerization reactions from monomeric diisocyanates of low molecular weight and varying volatility. Polyisocyanate also contain some amount of the diisocyanate monomer from which they were made. usually the content of monomer is less 0.5 percent for BMS product 操作不当－物理危害/化学危害 Ba flashpoint 操作不当 溶剂－所有溶剂型涂料的共同问题 Piso的反应活性 水－详细讲解涨桶危害过程 一滴水的故事 Caojing site – no such problem Sea shipment 通风避免形成可燃性蒸气 open flames, smoking, cutting and welding, hot surfaces, frictional heat, sparks, static 0－30C 存放 3层的原因 吸入、皮肤、眼睛 TDI 联大的例子 往往容易忽略慢性 溶剂的危害强调是任何溶剂型涂料系统都会有的问题 OEL的解释；反之会导致健康影响－接触量的问题 0.035=5ppb Ppb的概念 不再适合从事可能接触异氰酸酯的工作 一旦过敏，应立即停止从事接触异氰酸酯的操作，避免加重症状的可能性 过敏人群持续接触异氰酸酯可触发哮喘 哮喘：过敏性反应 严重可致命 所以固化剂中游离单体的含量高低对于健康的影响非常重要 This slide gives a comparison of monomeric diisocyanate to its according polyisocyanate. Their molecular structures, vapor pressure (since it’s a very important property which indicates to what level of risk may be cause by exposure to a hazardous atmosphere), and the hazards information as well. Take Desmodur N 3300 for e.g., a polyisocyanate derived from HDI. The molecule of N 3300 is actually a polyaddition product (HDI Trimer) of 3 molecules of monomeric HDI. Compared with its monomer the vapor pressure of polyisocyanate of N 3300 is extremely low (lowered to 10-8mbar). As you may can tell by this figure, usually polyisocyanates of higher molecular weight have no measurable vapor pressure. Therefore no inhalation problems (except spray application) inhere in comparison to its monomer. By comparing the vapor pressure and the hazards of mono-isocyanate and polyisocyanate, we can