(8337)--碳纳米管对水泥基材料微观结构及耐久性能的影响.pdfVIP

碳纳米管对水泥基材料微观结构及耐久性能的影响 摘 要：碳纳米管是一种性能优异的纳米材料，将其掺入水泥基材料中将会显著影响水泥基材料的微观结构及宏观性能。本 文系统总结和分析了国内外有关碳纳米管对水泥基材料微观结构和耐久性能的研究成果。讨论了碳纳米管对水泥基材料的水 化特性、孔结构、微裂缝、内部界面及抗碳化能力、抗离子侵蚀能力、抗冻融破坏能力的影响及作用机理。分析发现碳纳米 管通过成核作用促进了水化产物的生成、影响了水泥水化反应速率，并通过填充作用和桥联作用优化了水泥基材料的孔结构 和内部界面，阻碍了微裂缝的形成及扩展；此外，碳纳米管通过对水泥基材料微观结构的优化，提高了水泥基材料的抗碳化 能力、抗离子侵蚀能力和抗冻融破坏能力等耐久性能。目前，碳纳米管对水泥基材料微观结构及耐久性能影响的研究成果相 对较少，相关结论也未完全达成一致，因此，还需要进一步的深入研究。 Effect of Carbon Nanotubes on Microstructure and Durability of Cement-Based Materials 1,2 1 1,2 1 1,2 NIU Ditao , HE Jiaqi , FU Qiang , LI Dan , GUO Bingbing (1. School of Civil Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China; 2. State Key Laboratory of Green Building in Western China, Xi’an University of Architecture and Technology, Xi’an 710055, China) Abstract: Carbon nanotube is a kind of excellent nanomaterial. The incorporation of carbon nanotubes will affect the microstructure and macroscopic properties of cement-based materials. The research results about carbon nanotubes on the microstructure and durability of cement-based materials were analyzed. The effect of carbon nanotubes on the hydration characteristics, pore structure, micro-crack, internal interface, carbonization resistance, ion erosion resistance, frost and thaw resistance of cement-based materials and their mechanism were discussed. The results show that carbon nanotubes promote the generation of hydration products through nucleation and affect the hydration reaction rate of cement. The pore structure and internal interface of cement-based materials were optimized by the filling and bridging effects of carbon nanotubes, thus hindering the forming and expanding of micro-cracks Also, carbon nanotubes can improve the durability of the cement-based materials, such as carbonization resistance, ion er