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摇 2023年2月第1期摇 摇 摇 郑江华等:50kVA直流电弧炉处理卡尔多炉渣试验研究 ·59 ·
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金属结核[J]. 矿冶工程,1999,19(4):43-46. [J]. Mining and Metallurgical Engineering,1999,19(4):43-
MAO Yongjun,QU Shuguang,HE Zequan,et al. Reduction and 46.
smeltingof oceanpolymetallicnodulesin a DCelectricarcfurnace
Experimental study on treatment of Kaldor slag by50kVA DCEAF
1,2 1,2 1,2 1,2
ZHENGJianghua ,REN Xuegen ,MA Xiaodong ,ZONG Hongxin
(1.SKL of Nickel and Cobalt Resources Comprehensive Utilization,Jinchang737100,China;
2. NickelCobalt Research and Design InstituteJNMC,Jinchang737100,China)
Abstract:Firstly,thermodynamic calculation wasused to obtain the relationship between the Gibbsfree energy and
time of the mainreactionwhen smelting Kaldor slag. It showedthat under the condition of temperature750~1500益,
withcokeasreducingagentandlimestoneasflux,allmainreactionscouldoccur,andfinallycopper鄄nickelalloy and
calcium silicate slag could be obtained. On thisbasis,combinedwith difference in reducibility of different elements
in Kaldor slag,granularcoalwasusedasareducingagent,andKaldor slagwasselectivelyreducedandsmeltedina
DC electric arcfurnace to obtain qualifiedcopper鄄nickel alloy anddiscarded slag. Thetest resultsshowedthat under
the conditions of smeltingtemperatureof 1420益,reducingagentrateof 10%,fluxrateof 15%,andsettlingtimeof
60 minutes,high鄄grade copper鄄nickel alloyswere obtained,and the alloy gradeswere all greater than90郾00%;the
recovery ratesof copper and nickelwereboth greater than98郾50%,andthe content of nickel and copper inthe slag
werereducedto0郾15% and0郾32% respectively,achievingone鄄step extractionof valuablemetalsfromthe slag. The
research is conducive to improving the secondary resource recovery rate of non鄄ferrous metals,and l
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