疏水缔合交联聚合物微球的合成与表征的中期报告.docxVIP

疏水缔合交联聚合物微球的合成与表征的中期报告 摘要： 疏水缔合交联聚合物微球是一种多功能的载体材料，具有广泛的应用前景，例如在制药、催化剂、分离科学和生物医学应用中。本文介绍了一种新型的疏水缔合交联聚合物微球的合成方法。首先，通过自由基聚合反应合成了一种含有甲基丙烯酸甲酯（MAPTAC）单体的阳离子表面活性剂。然后，在MAPTAC阳离子表面活性剂的存在下，采用油包水的乳液聚合方法制备了聚苯乙烯(PSt)微球。最后，利用乙二醇二甲基丙烯酸酯(GDMA)和己二酸二羟乙酯(HEA)作为交联剂，在MAPTAC阳离子表面活性剂的存在下对PSt微球进行交联反应，制备了具有疏水性和缔合性的交联聚合物微球。本文还对合成的微球进行了表征，包括粒径、表面形貌、染料吸附能力和分散性等，结果表明所制备的微球具有良好的形貌和表面性质，且能够有效地吸附亚甲基蓝染料。该方法为制备具有多功能性的疏水缔合交联聚合物微球提供了一种新的思路。 关键词：疏水缔合交联聚合物微球；MAPTAC；乳液聚合；交联反应；亚甲基蓝 Abstract: Hydrophobic cross-linked polymer microspheres are a multi-functional carrier material with wide application prospects, such as pharmaceuticals, catalysis, separation science and biomedical applications. In this paper, a novel method for the synthesis of hydrophobic cross-linked polymer microspheres was introduced. First, a cationic surfactant was synthesized containing methylpropenoic acid methyl ester (MAPTAC) monomers by free-radical polymerization. Then, polystyrene (PSt) microspheres were prepared by oil-in-water emulsion polymerization in the presence of MAPTAC cationic surfactant. Finally, in the presence of MAPTAC cationic surfactant, PSt microspheres were cross-linked with ethylene glycol dimethacrylate (GDMA) and hexanediol diacrylate (HEA) as cross-linking agents to prepare cross-linked polymer microspheres with hydrophobicity and adhesion. The synthesized microspheres were characterized by particle size, surface morphology, dye adsorption capacity and dispersibility. The results show that the prepared microspheres have good morphology and surface properties, and can effectively adsorb methylene blue dye. This method provides a new idea for the preparation of multi-functional hydrophobic cross-linked polymer microspheres. Keywords: Hydrophobic cross-linked polymer microspheres; MAPTAC; emulsion polymerization; cross-linking reaction; methylene blue