无机化学与分析南京大学出版社第3章答案.pptVIP

第三章化学平衡与化学反应速率1:(2)SiCl4（l）+H2O(l)=SiO2(s)+4HCl(g)解[P(HCl)/Pθ]4[P(H2O)/Pθ]2(4)ZnS(s)+2H+(aq)Zn2+（aq）+H2S(g)[C(Zn2+)/Cθ]·[P(H2S)/Pθ][C(H+)/Cθ]23：解*Kθ=Kθ=3：解：COCl2(g)CO（g）+Cl2(g)始0.025mol00转0.025×16%mol0.004mol0.004mol平0.021mol0.004mol0.004mol0.004×8.314×6731.0PCl2=22.38kpaPCOCl2=117.50kpa(22.38/100)2117.50/100PCO=nRT/V==22.38KpaKθ==0.0434：解：△n=△PV/RT=(116-100)X1/(8.315X298)=0.0065molN2O4(g)2NO2(g)△n=1始0.04mol0mol转0.0065mol0.013Xmol0.0065mol平(0.04-0.0065)mol0.013molvN2O4=0.0335/(0.0335+0.013)=0.72vNO2=0.13/(0.0335+0.013)=0.28Kθ=(0.28x116)2/(0.72x116)=0.125：解：H2(g)+I2（g）2HI(g)始0.2mol0.2mol0转0.2Xmol0.2Xmol0.4Xmol平0.2-0.2Xmol0.2-0.2Xmol0.4Xmol0.4x·RTVPH2=PI2=(0.2-0.2x)RT/V(0.4X)2(0.2–0.2X)2X=0.7867I2的转化率为78.67%PHI=nRT/V=Kθ==54.