有机合成化学第七章.pdfVIP

SyntheticSyntheticOrganicOrganicChemistryChemistry

合成合成化学学

Lecture07PericyclicReactionI:

Diels-AlderReaction

DrDr.ShouyunShouyunYuYu

俞寿云副教授

1

ReadinggAssiggnment

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2

ClassificationofOrganicReactions

■Ionic

♣IIonsorellecttronsmoviingiinpaiirs

MeMeMeMe

heat

Br+BrCHO+BuBrBr

3CHOBu+

MeMe3

■Pericyclic

♣Cyclictransitionstructures

♣♣ConcertedConcertedbondbondforming/breakingforming/breaking(not(notalwaysalwayssynchronous)synchronous)

♣Singlestepwithnointermediate

OO

H

heat

+OO

■RadicalOHO

♣CCorrellatteddmovementtoffsiinglleellecttrons