μ-氧代四苯基双核铁卟啉一锅合成法的研究的开题报告.docxVIP

μ-氧代四苯基双核铁卟啉一锅合成法的研究的开题报告

Title:One-potsynthesisofμ-oxobridgedbis(tert-butylphenyl)-substituteddiiron(III)dimerporphyrin

Introduction:

Diironporphyrindimershavebeenextensivelystudiedduetotheiruniquepropertiessuchaselectrocatalysis,magnetism,andphotochemistry.Amongthem,diironporphyrindimerscontainingμ-oxobridgeareparticularlyinteresting,astheyexhibitefficientoxygenatomtransfercapability.Inthisstudy,weaimtodevelopasimpleandefficientone-potsynthesismethodforμ-oxobridgedbis(tert-butylphenyl)-substituteddiiron(III)dimerporphyrin.

Experimentalapproach:

Thesynthesiswillstartwiththereactionofiron(III)chloridewithtert-butylphenyl-substitutedporphyrininhotpyridine.Thereactionwillbecarriedoutunderinertatmospherewithrefluxfor24hours.Theresultingironporphyrincomplexwillthenbetreatedwithsodiumhydroxideinmethanoltoformthediiron(III)dimer.Finally,μ-oxobridgingwillbeachievedbyairoxidation,andtheproductwillbeisolatedbycolumnchromatography.

Expectedoutcomes:

Weanticipatetoobtainhighyieldoftheμ-oxobridgedbis(tert-butylphenyl)-substituteddiiron(III)dimerporphyrinusingthisone-potsynthesismethod.TheproductwillbecharacterizedbyvariousspectroscopictechniquessuchasUV-visabsorption,IR,andNMRspectroscopy.Wewillalsoevaluatetheoxygenatomtransfercapabilityofthesynthesizeddiiron(III)dimerusingamodelsubstrate.

Conclusion:

Insummary,theone-potsynthesisofμ-oxobridgedbis(tert-butylphenyl)-substituteddiiron(III)dimerporphyrinwillbecarriedoutbythereactionofiron(III)chloridewithtert-butylphenyl-substitutedporphyrinfollowedbysodiumhydroxidetreatmentandairoxidation.Thismethodwillofferasimpleandefficientrouteforthesynthesisofdiironporphyrindimerswithμ-oxobridge,whichcouldhavepotentialapplicationsinvariousfieldssuchascatalysisandenergyconversion.