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RAFT 聚合技术
RAFT聚合技术首先由Rizzardo等在第37届国际高分子大会上公布。该过程是一个可逆反应,称为可逆加成-裂解链转移过程(ReversibleAddition-FragmentationchainTransfer),也就是RAFT。RAFT体系适用的单体种类多,聚合所需温度较低,可制备较高分子量的窄分布聚合物。因此,具有广阔的应用前景。
RAFTtechnology
CSIROandDuPonthavedevelopedaninnovativetechnologyknownasRAFT(forReversibleAdditionFragmentationchainTransfer),whichallowsforthesynthesisofspeciallydesignedpolymericmaterialswithenhancedproperties.CSIROhaslicensedthistechnologytoStremto
makeavailabletoyouforresearchpurposes.
RAFTtechnologyisasophisticatedformofcontrolledfreeradicalpolymerization.Oftenknownaslivingpolymerization(itcanbestoppedandrestartedatanytime)thistechnologyenablesthe synthesis of tailored polymers with unprecedented control over composition andarchitecture.
Polymersmaybesynthesizedmorereadily,usingRAFTtechnology,
Withpredeterminedmolecularweightandnarrowmolecularweightdistributionsoverawiderangeofmonomersandreaction
conditions,
With reactive terminal groups that can be purposely manipulated, including further
polymerization,
Withcomplexarchitecture,includingABdiblock,ABAtriblock,graft,star;gradientandbranchedpolymers(seeFigI),
Thatarebasedonscaleablemanufacturingprocessesutilizingconventionalprocessing
equipment.
RAFTtechnologycanbeusedwithawiderangeofmonomersandmonomermixtures,andcanbeusedinallmodesoffreeradicalpolymerization,includingsolution,emulsionandsuspensionpolymerizations.Thisallowsfor anunlimitedarrayoftailoredcompositionsandcomplexarchitecturesunderstandardconditions.
TheRAFTprocess
ImplementingtheRAFTprocesscanbeassimpleasintroducingasuitablechaintransferagent,knownasaRAFTAgent(seeFig 2), into conventional freeradical polymerization, while
employingplantandequipment.TheRAFTAgentsallowforthepreparationofpolymerswithlow polydispersity, well-defined microstructure and predeter
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