齐齐哈尔大学化学工程与工艺专业毕业设计论文(年产5万吨丙酮车间丙酮精馏工段初步设计).pdfVIP

摘要

环己酮又名尼龙酸，是己二酸生产过程产生的副产物，仅国内己二酸生产企业每年就副产

混合二元酸40-60万吨。由于其含杂质、水分多，颜色呈绿色或黄褐色，难以利用。国外一般

将其送进污水处理装置作焚烧或填埋处理；国内有采用重结晶法回收，但回收率低于60％，废

水量较大，不仅对环境造成污染，而且也造成资源的浪费。为了物尽其用，本文开展了应用基

础研究以C4-C6混合二元酸为原料、对甲苯磺酸为催化剂，制备混合二元酸二甲酯，并利用减

压精馏得到纯净的二甲酯。实验中考查了各种反应的影响因素，并利用制备的混合二甲酸二甲

酯与异辛醇进行酯交换制备混合二元酸二异辛酯。

关键词：环己酮；环己烯；酯交换；混合二元酸二甲酯

Abstract

Mixeddibasicacid(DBA),alsoknownasnylonacid,adipicacidproductionprocessby-products,

onlydomesticproducersofadipicacidby-productmixtureineachofdicarboxylicacid40-60million

tons.Becauseofitsimpurities,watercontent,thecolorgreenorbrown,itisdifficulttouse.Foreign

generaltobesenttosewagetreatmentplantforincinerationorlandfilling;domesticuse

I

recrystallizationrecovery,butrecoverywaslessthan60%,largeamountofwastewater,notonly

pollutetheenvironment,butalsoawasteofresources.Inordertomakethebestuse,thisapplication

ofbasicresearchcarriedouttoC4-C6dicarboxylicacidasrawmaterialmixture,p-toluenesulfonic

acidascatalyst,preparedbymixingtwoyuanacidester,andtheuseofvacuumdistillationtogetpure

dimethylester.Experimentexaminedtheresponseofvariousfactors,anduseamixtureofdimethyl

esterpreparedwithdifferentoctanolpreparedbymixingtwoyuanfortransesterificationethylhexyl

sebacate.

Accordingtotheexperimentaldatashowthat,byesterificationofdicarboxylicacidmixture

separationprocessrouteisfeasible.Esterificationoftheappropriatereactionconditions:reactiontime

5.0h,alkydmolarratioof6:1,1.0%mixedacidcatalyst,inthiscondition,binaryacidesteryieldof

89%.Estersderivedfromcrudeesterificationcanbecarriedoutunderthepressureof40mmHgvacu

esterificationcanbeeffectivelyseparatedmixeddicarboxylicacid.

Keywords:mixeddiba