加氢精制装置课件.pptVIP

PetroleumandChemicalEngineeringSystemFundamentsSectionVHydroRefiningUnit加氢精制装置Matingxia

Hydrorefiningunit加氢精制装置Hydrorefiningunitisageneraltermforvarioushydrorefiningoilproductstomodifyinthehydrogenpressure加氢精制各种油品在氢压下进行改质的总称

ThePurposeofhydrorefining加氢精制的目的——totransformsulfur,oxygen,nitrogenandotherharmfulimpuritiesintheoilproductsintohomologoushydrogensulfide,water,ammoniaundertheroleofhydrogenpressureandcatalyst,andthengetthemremoved.Besides,italsoaimstoachievethehydrogenationandsaturationofalkeneandalkadieneaswellaspartialhydrogenationandsaturationofaromatichydrocarbon,andeliminatepartialmedalandasphaltimpuritiesinordertoimprovethesmell,colorandstabilityofoilproducts,preventcorrosion,furtherimproveproductqualityandmeettherequestforutilization.其目的是在氢压和催化剂作用下使油品中的硫、氧、氮等有害杂质转变为相应的硫化氢、水、氨而除去，并使烯烃和二烯烃加氢饱和、芳烃部分加氢饱和，部分金属及沥青杂质得以脱除，以达到改善油品的气味、颜色和安定性，防止腐蚀，进一步提高产品质量，满足油品的使用要求。

Hydrorefiningcangenerallybedividedintotwocategoriesaccordingtoitsrefiningpurpose:oneistodirectlyproducecleanfueloil;theotheristoprovidehigh-qualityrawmaterialsforotherprocessesordevices.加氢精制按其目的一般可以分为两类，一类是直接生产清洁燃料油；另一类则是为其它工艺或装置提供优质原料。

Themainreactionsofhydrorefining加氢精制的主要反应hydrodesulfurization加氢脱硫hydrodenitrogenation加氢脱氮hydrodeoxygenation加氢脱氧hydrodemetallation(HDM)加氢脱金属olefinsaturation烯烃饱和

hydrogenationunit柴油加氢精制组成单元reactionunitofheatingfurnace加热炉反应单元productseparation产品分离单元recyclinghydrogenunit循环氢单元dry-gasdesulfurizationunit干气脱硫单元expansionpartsmembraneseparationunit膜分离单元柴油加氢精制装置由加热炉反应单元、产品分离单元和循环氢单元等三部分组成。作为扩充部分有：干气脱硫单元，膜分离单元等

Theprocessofhydrogenationcomplementrefining(positivesequence)hydrogenationcomplementrefiningsolventrefiningdewaxedoileachwiredistillateraffinateoillubricantbaseoildeasphaltedoilwax-bearingoilTheprocessofhydrogenationcomplementrefining(antitonesequence)

TheprocessofHydrogenation