《新能源技术与材料》第12讲Polymer solar cell.pptx

Polymersolarcell

ContentsAbriefintroductionofPSC1invertedpolymersolarcell2othersworksinIPSC3

1.AbriefhistoryofPSC1839Becquerelobservedthephotoelectrochemicalprocess1958KearnsandCalvinworkedwithmagnesiumphthalocyanines(MgPh),measuringaphotovoltageof200mV1977Heeger.et.al.usedAsF5、I2dopedpolyacetylene,greatlyimproveitsconductivity1986C.W.Tangpublishedthefirstdouble-deckheterojunctionPVdevice1993N.S.Saricifticmadethefirstpolymer/C60heterojunctiondevice1995Yu/Hall.madethefirstbulkpolymer/polymerheterojunctionPV.1994Yu.madethefirstbulkpolymer/C60heterojunctionPV.2001Shaheen.controlactivelayermorphologybychoicedifferentsolvents2003Padinger.developedapostproductiontreatmentthatimprovestheperformanceofPSCbasedonP3HT:PCBM2007Kimet.al.EfficienttandempolymersolarcellsusedP3HTandPCPDTBTasdifferentlightabsorptionlayer2010YongyeLianget.al.DesignanewkindofnarrowbandgappolymersPTB-72011YongCao.incorporatinganalcohol/water-solubleconjugatedpolymerascathodeinterlayer(PFN).2012YangYang.TandempolymersolarcellswithHighef?ciencyof10.6%2013VinayGupta.BaasETL,P-DTS(FBTTh2)2/PC71BMasactivelayer,PEC=9.02%

Typicaldevicecon?gurationsofPSCCDeibelandVDyakonov.Rep.Prog.Phys.2010.73.1-38

NoverlstructureofPSCa.Solution-processedtandemPSC(regular)b.StretchablePSCSista,S.etal.Adv.Mater.22,380–383(2010).Lipomi,D.?J.etal.Adv.Mater.23,1771–1775(2011).c.InvertedPSCRuixiangPeng.et.al.ThinSolidFilms545(2013)424–428

MechanismandparametersCarstenDeibelandVladimirDyakonov,Rep.Prog.Phys.2010,73,1-38.

I-VcurveandEquivalentcircuitCarstenDeibelandVladimirDyakonov,Rep.Prog.Phys.2010,73,1-38.

MorphologyinPSCCDeibelandVDyakonov.Rep.Prog.Phys.2010.73.1-38a,Tappingmodeatomicforcemicroscopyimage