气相色谱法测定秀珍菇中5种有机氯农药残留研究.pdf

气相色谱法测定秀珍菇中5种有机氯农药残留研究

谢正林，吴梦雅，赵婉宁，沙莎，陈永存，宗秋月

(江苏农林职业技术学院，江苏句容212400)

摘要：文章通过优化前处理的振荡时间、萃取时间及氮吹时间，建立了秀珍菇中五氯硝基苯、三氯杀螨醇、联苯菊酯、氯

菊酯、氰戊菊酯5种农药多残留量测定方法。结果表明：前处理最佳提取条件为振荡时间2min、萃取时间为20.5min、氮

吹时间28.5min。此方法测定以上5种有机氯农药检出限分别为：0.016μg/kg、0.029μg/kg、0.056μg/kg、0.017μg/kg、

0.081μg/kg。添加标准农药回收实验验证：5种农药的平均回收率为：76.3%～106.2%，RSD值为1.7%～9.7%，均达到气

相色谱检测要求，具备秀珍菇未知样检测以上5种农药的检测能力。实验表明，此方法仪器检测灵敏度高，回收率和精

密度高，且成本低易于操作，可用于秀珍菇此5种农药残留检测。

关键词：气相色谱法；秀珍菇；农药多残留

中图分类号：O65，X592 文献标志码：A文章编号：1008-4800(2024)17-0053-04

DOI:10.19900/ki.ISSN1008-4800.2024.17.014

StudyofFiveOrganochlorinePesticideResiduesinXiuzhenMushroomby

GasChromatography

XIEZhenglin,WUMengya,ZHAOWanning,SHASha,CHENYongcun,ZONGQiuyue

(JiangsuVocationalandTechnicalCollegeofAgricultureandForestry,Jurong212400,China)

Abstract:Amethodforthedeterminationofpentachloronitrobenzene,dicofol,bifenthrin,permethrinandfenvalerateinXiuzhen

mushroomwasestablishedbyoptimizingtheoscillatingtime,extractiontimeandnitrogenblowingtimeofpretreatment.

Theresultsshowedthattheoptimalextractionconditionswereoscillationtimeof2min,extractiontimeof20.5minand

nitrogenblowingtimeof28.5min.Thedetectionlimitsoftheabovef iveorganochlorinepesticideswere0.016μg/kg,0.029μg/kg,

0.056μg/kg,0.017μg/kgand0.081μg/kg,respectively.Theexperimentalresultsshowedthattheaveragerecoveriesofthe

f ivepesticideswere76.3%～106.2%,andtheRSDvalueswere1.7%～9.7%,allofwhichmetthedetectionrequirementsofgas

chromatography,andtheunknownsamplesofXiuzhenmushroomwerecapableofdetectingtheabovef ivepesticides.The

experimentshowsthatthemethodhashighsensitivity,highrecoveryandprecision,lowcostandeasyoperation,andcanbeused

forthedetectiono