基础油颜色异常的原因分析及解决方案.pdfVIP

2024年6月润滑油第39卷第3期

Jun.2024LUBRICATINGOILVol.39,No.3

DOI:10.19532/21-1265/tq.2024.03.010

基础油颜色异常的原因分析及解决方案

徐宁宁，王海燕，孙洪鑫，方磊

（中国石油化工股份有限公司济南分公司，山东济南250101）

摘要：通过对基础油生产原料热稳定性和溶剂组成解析，判断基础油颜色变深且发生深浅可逆变化是由溶剂中氮质量浓度异

常偏高造成的。分析了溶剂系统中氮元素的可能性来源，针对性排查氨冷系统，推断溶剂氮质量浓度偏高是由于脱蜡段氨冷

换热器管程发生内漏，致使氨液进人了溶剂系统。根据分析结果，切换氨冷换热器4d后，基础油颜色恢复正常。对置换下来

的氨冷换热器进行检修，确认管程发生了腐蚀性内漏

关键词：基础油；溶剂；颜色；氮质量浓度；氨

中图分类号：TE626.9文献标识码：A

AnalysisoftheAbnormalColorofBaseOilandSolutions

XUNing-ning,WANGHai-yan,SUNHong-xin,FANGLei

(SINOPECJinanCompany,Jinan,Shandong250101,China)

Abstract:Byanalyzingthethermalstabilityofrawmaterialsandthecompositionofsolventsinbaseoilproduction,itwas

determinedthatthedeepeningofthebaseoilcoloranditsreversiblechangeswerecausedbyanabnormallyhighnitrogen

massconcentrationinthesolvent.Thepossiblesourcesofnitrogenelementsinthesolventsystemwereanalyzed,anda

targetedinvestigationoftheammoniarefrigerationsystemwasconducted.Itwasinferredthatthehighnitrogenmasscon-

centrationinthesolventwasduetointernalleakageintheammoniarefrigerationheatexchangerofthedewaxingsection,

leadingtotheentryofammonialiquidintothesolventsystem.Basedontheanalysisresults,afterswitchingtheammonia

refrigerationheatexchangerforfourdays,thecolorofthebaseoilreturnedtonormal.Uponinspectionofthereplacedam-

moniarefrigerationheatexchanger,itwasconfirmedthatcorrosion-inducedinternalleakagehadoccurredinthetubepass

oftheheatexchanger.

Keywords:baseoil;solvent;color;nitrogencontent;ammonia

0引言油外观异常周期内，各相关物料性质如表1所

某炼化公司采