镇海炼化硫磺回收制二硫化碳生产项目2-Abstract.docVIP

TheProjectofUsing72kt/aSulfurtoProduceCarbonDisulfidefromZRCCProjectDesignSummary

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CONTENT

TOC\o1-3\h\z\u1.Introduction 1

2.ProcessPlanning 2

2.1Rawmaterialpretreatment 2

2.2Clausdesulfurizationsection 3

2.3Theexhaustgashydrogenationreductionsection 5

2.4Carbondisulfideproductionsection 6

3.Energy-savingdesign 8

3.1Heatexchangernetworkoptimization 8

3.2Methanemembraneseparationtechnology 9

4.PlantlocationLayout 12

5.Economicanalysis 14

5.1Netcashflow 14

5.2Estimationofstaticbenefitindicators 14

6.Conclusions 15

TOC\o1-3\h\z\u

1.Introduction

TheprojectistodesignasetofdesulfurizationequipmentfortheZRCC,andalsousingtheproduceofdesulfurizationtoproductcarbondisulfide.TheequipmentusesthegasbesidessulfurelementfromtheZRCCtomeetemissionsstandardsandproducttheproduce.Thisprocessincludesrawmaterialpretreatment,Clausdesulphurization,tailgashydrogenationreductionandsulfurmethanesynthesisfoursections.Thedesignprocesscontains202,000tonsofsulfur-containingwastegas,andtherecoveryofsulfuris72,000tonsperyear,producing85,000tonsperyearofcarbondisulfide,andthedesulfurizationrateis99.96%,producinga99.1%purity.Theoverallprocessflowchartisasfollows.

Fig.1.1theoverallprocessflowchart

2.ProcessPlanning

Thisprocesscomprehensiveutilizationtothetotalsulfur-containingwastegasfromtheZRCC,thepretreatmentofrawmaterialsgathersthegas,thenwiththeoxygenenrichedairaccordingtotheproportionintotheClaussystemofdesulfurization,exhaustintothehydrogenationprocessafterreaction,thesulfurcomponentwillbeconvertedtohydrogensulfide,thenextusingthePCenrichthehydrogensulfideinposteriorcirculation.TheproducesulfurfromtheClaussectionisvaporizedandblendedwithnaturalgasintoareactortoproducecarb