范文-Ag3PO4 g-C3N4复合光催化剂的制备及其性能研究.docxVIP

摘要

由于工业化进程的加速，水体污染的问题日益突出，尤其是有机染料的排放给环境和人类健康带来了严重挑战。因此，光催化技术作为一种高效且环保的污染物处理技术备受瞩目。本论文主要介绍了溶剂热法制备Ag3PO4，以三聚氰胺为原料通过热聚合法制备g-C3N4，采用物理混合方法制备Ag3PO4/g-C3N4复合催化剂的过程，并通过对复合光催化剂的表征分析，确认了Ag3PO4和g-C3N4的成功复合。探究了不同配比的复合光催化剂对甲基橙、罗丹明B和亚甲基蓝三种有机染料的光催化降解效果。实验结果表明，随着Ag3PO4在复合光催化剂中比例的增加，光催化活性先增加后减少，当Ag3PO4的比例达到30%时，光催化剂展现出最佳的降解效率，这表明适当的Ag3PO4含量有助于增强复合催化剂对可见光的吸收，提高光生载流子的产生和分离效率，从而提升了光催化性能。本研究为新型高效光催化剂的设计和开发提供了宝贵的实验数据和理论依据。对于解决环境污染问题，特别是水体中有机染料的降解，具有重要的实际意义和应用价值。

关键词：光催化剂；Ag3PO4/g-C3N4；有机染料降解；可见光响应

Abstract

Withtheaccelerationofindustrialization,theproblemofwaterpollutionisincreasinglyserious,especiallythepollutionoforganicdyesposesaseverechallengetotheenvironmentandhumanhealth.Photocatalytictechnology,asanefficientandenvironmentallyfriendlypollutanttreatmentmethod,hasreceivedwideattention.ThepurposeofthisstudywastoexplorethepreparationofAg3PO4/g-C3N4compositephotocatalystsanditsphotocatalyticdegradationoforganicdyesundervisiblelightirradiation,soastoprovideatheoreticalandexperimentalbasisforthedevelopmentofhighlyefficientvisiblelight-responsivephotocatalysts.TheAg3PO4/g-C3N4compositephotocatalystwassuccessfullypreparedbyasimplephysicalmixingmethod,andthesuccessfulrecombinationofAg3PO4andg-C3N4wasconfirmedbycharacterizationanalysisofthephotocatalyst.Thephotocatalyticdegradationeffectofmethylorange,rhodamineBandmethylenebluewasstudied.ExperimentalresultsshowthatwiththeincreaseoftheproportionofAg3PO4inthecompositephotocatalyst,photocatalyticactivityincreasedafterdecrease,whentheproportionofAg3PO4reached30%,thebestdegradationefficiency,whichshowsthattheappropriateAg3PO4contentcanenhancetheabsorptionofcompositephotocatalystvisiblelight,improvelightcarriergenerationandseparationefficiency,soastoimprovethephotocatalyticperformance.Therefore,throughthepreparationofAg3PO4/g-C3N4compositepho