喷射电沉积制备超疏水复合涂层及其耐腐蚀性能研究.pdfVIP

HotWorkingTechnology2020,Vol.49,No.12

鲁表面改性技术參

喷射电沉积制备超疏水复合涂层

及其耐腐蚀性能研究

姜凌云，陈劲松，鲍恩泉，郭建

(淮海工学院机械与海洋工程学院，江苏连云港222005)

摘要：采用两步法实现金属铜表面的超疏水化，首先采用喷射电沉积法在金属铜表面获得微纳米复合粗糙结构，

然后利用0.03mol/L的肉豆蔻酸-乙醇溶液疏水化改性得到超疏水复合涂层。利用接触角测量仪、SEM、XRD和FT-IR

(傅里叶变换红外光谱仪）表征超疏水层的润湿性、微观形貌和化学成分。测试极化曲线，分析试样的耐腐蚀性。结果表

明：当电流密度400A/dm2、扫描速度14mm/min和电解液流量1.6L/min时可在预沉积层上制备得到具有微纳粗糙结

构的镀层。经改性后获得超疏水表面，接触角达到154.7°。超疏水表面具有耐腐蚀性能，可为基体提供防护作用。

关键词：喷射电沉积；超疏水；耐腐蚀

DOI:10.14158/j.cnki.1001-3814.

中图分类号：TG174.4文献标识码:A文章编号：1001-3814(2020)12-0082-04

ResearchonFabricationofSuperhydrophobicCompositeCoating

byJetElectrodepositionandItsCorrosionResistance

JIANGLingyun,CHENJinsong,BAOEnquan,GUOJian

(SchoolofMechanicalandOceanEngineering,HuaihaiInstituteofTechnology,Lianyungang222005,China)

AbstractThesuperhydrophobicization：ofthecoppersurfacewasachievedbytwo-stepprocess.Firstly,themicro-nano

compositeroughstructurewasobtainedonthesurfaceofmetalliccopperbyjetelectrodeposition,andthena

superhydrophobiccompoundcoatingwasobtainedbyhydrophobizationwith0.03mol/Lmyristicacid-ethanolsolution.The

wettability,morphologyandchemicalcompositionofthesuperhydrophobiclayerwerecharacterizedbycontantanglemeter,

SEM,XRDandFT-IRspectrometer.Thecorrosionresistanceofthesamplewasanalyzedbyusingpolarizationcurve.The

resultsshowthatthemicro-nanoroughnessstructurecanbepreparedont