Cu、Ga和C掺杂对MnAl合金相结构及磁性能的影响.pdfVIP

HotWorkingTechnology2019,Vol.4No.4

Cu、Ga和C掺杂对MnAl合金相结构

及磁性能的影响

瞿晓丹，陈星星，安海强，金昊旳，苏昆朋

(杭州电子科技大学材料物理研究所，浙江杭州310018)

摘要：研究Cu、Ga、C元素掺杂的MnAl合金的相结构和磁性能。结果表明：在Cu或者Ga掺杂的MnAl合金

中加入C元素，有助于磁性相T-MnAI的形成。MnsoAbTGa’G粉末的饱和磁化强度(MJ随着球磨时间的增加而减小，

矫顽力(民)随着球磨时间的增加先增大后减小。球磨前Mn5OAL(7Ga3C3合金(10009x20h)样品的饱和磁化强度为

89.98Am2/kg,约为其理论饱和磁化强度值144Am2/kg的62.5%；获得最好磁性能是在粉末球磨lh后，=51.91

Am2/kg,HC=155.2kA/mo

关键词：无稀土永磁;MnAl合金；热处理;饱和磁化强度；矫顽力

DOI:10.14158/j.cnki.1001-3814.2019.04.020

中图分类号:TG145.TG156文献标识码：A文章编号:1001-3814(2019)04-0082-05

EffectsofCu,GaandCDopingonPhaseStructure

andMagneticPropertiesofMnAlAlloy

QUXiaodan,CHEXingxing,AHaiqiang,JIHaoyun,SUKunpeng

(InstituteofMaterialPhysics,HangzhouDianziUniversity,Hangzhou31001China)

Abstract:ThephasestructureandmagneticpropertiesofMnAlalloysdopedwithCu,GaandCelementswere

investigated.TheresultsshowthatthecarbonadditionpromotestheformationoftheT-MnAlphaseinMnAlalloysdoped

withCuorGa.Thesaturationmagnetization(M$)ofMn5oA147Ga3C3powdersdecreaseswiththeincreaseofthemillingtime,

andthecoercivity(Z/c)firstlyincreasesandthendecreaseswiththeincreaseofmillingtime.MsforMn5oA147Ga3C3bulk

speciment(1000°Cx20hheattreatment)beforemillingis89.98Am2/kg,whichisabout62.5%ofitstheoreticalMsvalue(144

Am2/kg).andthentheoptimalmagneticproperties,suchasAfs=51.91Am2/kg,7/c=155.2kA/m,canbeobtainedfromthe

powdersballmillingforlh.

Keywords:non-rareearthpermanentmagnet;MnAlalloy;heattreatment;saturationmagnetization;coercivity

稀土资源储量有限，