铜_石墨烯复合材料的制备及性能研究.pdfVIP

HotWorkingTechnology2019,Vol.48,No.4

铜/石墨烯复合材料的制备及性能研究

周千广，彭倚天

(东华大学机械工程学院，上海201620)

摘要：为了提高铜和石墨烯之间的界面结合强度，采用化学镀的方法使石墨烯表面均匀包裹纳米铜颗粒，然后利

用粉末冶金工艺制备铜/石墨烯块体复合材料。本文研究了石墨烯含量对复合材料硬度和致密度的影响，并通过

HSR-2M高速往复摩擦磨损试验机研究了铜/石墨烯块体复合材料的摩擦磨损性能。结果表明：石墨烯的加入对铜/石

墨烯块体复合材料的硬度有显著的提高，但致密度随石墨烯含量的增加而降低，块体复合材料的摩擦系数和磨损率均

低于未增强的纯铜。

关键词：铜/石墨烯复合材料；粉末冶金工艺；硬度；摩擦系数；磨损率

DOI:10.14158/j.cnki.1001-3814.2019.04・027

中图分类号:TB333文献标识码：A文章编号:1001-3814(2019)04-0108-04

StudyonFabricationandPropertiesofCopper/GrapheneComposites

ZHOUQianguang,PENGYitian

(CollegeofMechanicalEngineering,DonghuaUniversity,Shanghai201620,China)

Abstract:Thecopperparticleswereevenlydistributedonthegraphenesurfacebyusinganelectrolessplatingmethodin

ordertoimprovetheinterfacialbondingstrengthbetweenthegrapheneandthecoppermatrix.Thenthemixedpowderof

copper/grapheneandcoppermatrixwasfabricatedintocopper/graphenebulkcompositesbypowdermetallurgyprocess.The

effectsofdifferentgrapheneoxidecontentsonthehardnessandrelativedensityofthecompositeswereinvestigated.Andthe

frictionandwearperformanceofthecompositeswereexecutedonaHSR-2Mhigh-speedreciprocatingtribo-tester.The

resultsshowthattheadditionofgraphenehasasignificantimprovementinhardnessofthecomposites,buttherelativedensity

decreaseswiththeincreaseofgraphene,andthebulkcompositesexhibitealowerfrictioncoefficientandwearratecompared

withtheunreinfbrcedcopper.

Keywords:copper/graphenecomposites;powdermetallurgyprocess;hardness;frictioncoefficient;wearrate

铜具有良好的导电、导热和易于成型性，但其硬采用球磨法和大异步轧制技术制备了铜基石