化学镀Ni-B镀层对Al-Cu-Mg合金组织和腐蚀性的影响.pdfVIP

HotWorkingTechnology2016，Vo1．45，No．8

化学镀Ni—B镀层对AI—Cu—Mg合金

组织和腐蚀性的影响

陈来，刘志义，林亮华，杨荣先

(中南大学材料科学与工程学院，湖南长沙410083)

摘要：采用化学镀法在A1．Cu—Mg合金表面制备Ni．B镀层，通过扫描电镜(SEM)2~X射线衍射分别对镀层形貌

及结构进行了分析。研究了在3．5％NaC1溶液中NiB镀层对Al—Cu．Mg合金腐蚀形为的影响。结果表明，Ni—B镀层为结

构致密的非晶合金，经热处理后镀层发生明显晶化转变，分解成面心立方(fcc)Ni相及大量的Ni相，使镀层硬度明

显提高。在腐蚀介质中，Ni—B镀层较Al—Cu—Mg合金腐蚀电流密度降低近一个数量级。Ni—B镀层试样的腐蚀过程主要

由电荷传递过程控制，且未发现微孑L腐蚀现象，因此可有效阻碍腐蚀液对基体的直接侵蚀从而提高Al—Cu—Mg合金的

耐腐蚀性。

关键词：A1．Cu．Mg合金；化学镀；Ni．B镀层；耐腐蚀性

DOI：10．141580．enid．1001-3814．2016．08．047

中图分类号：TG146．2；TG174文献标识码：A文章编号：1001．3814(2016)08．0176—04

EffectofElectrolessPlatedNi—BCoatingonMicrostructureandC!orrosion

Proerties0fAl—Cu—MgAlloy

CHENLai，L1UZhiyi，LINLianghua，YANRongxian

(SchoolofMaterialScienceandEngineering，CentralSouthUniversity，Changsha410083，China)

Abstract：Ni—BalloycoatingwasdepositedonA1-Cu—Mgalloybyelectrolessnickelplating．Thesurfacemorphology

andstructureofNi—BcoatingwereanalyzedbyusingSEMandXRD，respectively．TheinfluenceofNi—Bcoatingonthe

corrosionbehaviorofA1一Cu-Mgalloywasinvestigated．TheresultsshowthatelectrolessNi-BCOatingwithlowporosityis

amorphousandcrystallizedtolargeamountoffacecenteredcubic(fee)NiandNiphaseafterheatrteatmentat300℃forlh，

whichcansignificantlyincreaseitssurfacemicrohardness．ThecorrosioncurrentdensiytofNi—Bcoatingisaboutoneorder

lowerhtnathatofA1一Cu—Mgalloyincorrosionmedium．Thecorrosionprocessisconrtolledbychargetransferstepwithno

evidenceofpittingcorrosion，hence，thecorrosionresistnaceofA1一Cu—Mgalloyimprovesbyprotectingthesubstratefromthe

erosionofNaC1solution．

Keywords：A1一Cu—Mgalloy；electrolessplating；Ni—Bcoating；corrosionresistance

A1．Cu—Mg合金具有高的比强度、低的弹性模量