球墨铸铁粉末渗硼的耐蚀性能研究.pdfVIP

HotWorkingTechnology2014，Vo1．43，No．12

球墨铸铁粉末渗硼的耐蚀性能研究

赵景浩．罗宏

(1四川理工学院材料与化学工程学院，四川自贡643000；2．材料腐蚀与防护四川省高校重点实验室，四川自贡

643000)

摘要：对球墨铸铁在不同温度和时间下分别进行渗硼处理，采用金相显微镜观察了渗硼层的形貌，测定了渗硼层

的厚度；用显微硬度计测定了渗硼层的表面硬度；用x射线衍射仪分析了渗硼层的物相组成；用扫描电镜测定了渗硼

层表面元素含量；并在10％的HCI、H2SO4、HNOhNaCI、NaOH溶液中做了耐蚀性对比试验。结果表明：渗硼层厚度均

匀，呈齿状结构与基体结合牢固，渗硼层主要由Fe：B单相组成；在950℃下保温不同时间，渗硼层的厚度及硬度均随时

间的增长而逐渐增大；在不同温度下保温5h时，渗硼层厚度随温度的升高而逐渐增大，渗硼层的硬度随温度的升高先

增大后减小，除HNO外，渗硼处理后试样的耐蚀性均比未渗硼的试样的耐蚀性能好。

关键词：球墨铸铁；渗硼；厚度；显微硬度；耐蚀性

中图分类号：TG156．1文献标识码：A文章编号：1001．3814(2014)12．0166—04

StudyonCorrosionResistanceofDuctileCastIronwithBorideLayer

ZHAOJinghao．LUOHong，2

(1．InstituteofMaterialandChemicalEngineering，SichuanUniversityofScienceandEngineering，Zigong643000，

China；2．MaterialCorrosionandProtectionKeyLaboratoryofSichuanProvnice，Zigong643000，China)

Abstract：DuctilecastIronwasboridedatdifferenttemperatureanddifferenttime．Theboridelayerofthe

cross—sectionmorphologywasobservednadthethicknessofhteboridelayerwastestedbymicroscope．Thesurfacehardness

ofboridelayerwastestedbyVickersharndesstester．ThephasecompositionofboridelayerwasnaalyzedbyXRD．element

contentoftheboridelayerwastestedbyEDS，andthecorrosionresistancetestsoftheboridelayerwerecarriedoutin10％

HCI，H2SOHNO3，NaC1，NaOH．Theresultsshowthatthehticknessofhteboronizinglayerisdistributed；boridelayeris

firmlybondedtothesubstrateasthedentatestructure．BoridelayerismainlycomposedofFe2B．Whenthetemperatureis

950℃，thethicknessandhardnessoftheboronizinglayergraduallyincreasewihthteincreaseoftime．Whenhtetimeis5h，

thethicknessoftheboronizinglayergraduallyincreaseswihthteincreaseoftemperature，buttheharndessoftheboronizing

layerincreasesatfirstanddecreaseslaterwihthteincreaseoftempe