稀土镁合金、AZ31及AZ91负极材料耐腐蚀性能及放电行为的比较.pdfVIP

《热加工工艺》2018年5月第47卷第10期

稀土镁合金、AZ31及AZ91负极材料

耐腐蚀性能及放电行为的比较

李慧明，谢刚李荣兴，，俞小花-，侯彦青t

(1．昆明理工大学冶金与能源工程学院，云南昆明650000；2．昆明冶金研究院，云南昆明6500001

摘要：通过对动电位极化曲线、电化学阻抗谱图、SEM形貌的分析，研究了AZ31、AZ91和稀土镁合金在8．0％

(质量分数)NaCI溶液中的腐蚀行为。并将上述三种镁合金组装成电池，在8．0％NaC1溶液中进行恒流放电测试。结果表

明：三种负电极的耐蚀性是稀土合金AZ3lAZ91；浸泡48h后稀土镁合金的表面裂纹最少，腐蚀程度最轻．而AZ91

负极的腐蚀程度最严重，表面裂纹较深；稀土合金的放电时间最长，达到800min，AZ31为710min，AZ91为660min。

关键词：镁合金；中性电解液；耐腐蚀性；恒流放电

DOI：10．14158／j．cnki．1001-3814．2018．10．015

中图分类号：TG230．2文献标识码：A文章编号：1001．3814(2018)10．0057．05

ComparisonofCorrosionResistanceandDischargeBehaviorofRareEarth

MagnesiumAlloy，AZ31andAZ91NegativeElectrodeMaterials

LIHuiming，XIEGang，LIRongxing，YUXiaohua，HOUYanqing

(1．FacultyofMetallurgicalandEnergyEngineering，KunmingUniversiytofScienceandTechnology，Kunming650000，

China；2．KunmingMetallurgicalResearchInstitute，Kunming650000，China)

Abstract：ThecorrosionbehaviorsofAZ31．AZ91nadrareearthmagnesiumalloysin8．0％NaCIsolutionwere

investigatedbypotentiodynamicpolarizationcurve，electrochemicalimpedancespecrtoscopy(EIS)andscanningelecrton

microscopy(SEM)．Theabovethreemangesiumalloyswereassembledintoba~edes．Theconsatntcurrentdischargetestin

8．0％NaCIsolutionwascarriedout．Theresultsshowthatthecorrosionresisatnceofthethreekindsofnegativeelecrtodeis

rareearthalloyAZ31AZ91．Thesurfacecrackofrareearthmangesimualloyistheleastnadthecorrosiondegreeisthe

lightestafterimmersionfor48h．However，thecorrosionofAZ91negativeelecrtodeisthemostserious，andhtesurfacecrack

isdeeper．Thedischargetimeoftherareearthalloyishtelongest，reaching800min，AZ31is710min，andAZ91is660min．

Keywords：mangesimualloy；neutralelecrtolyte；corrosionresistance；constantcurrentdischarge

传统能源的消耗时常伴随着环境的日益恶化，稳定，电极容易变形且自腐蚀率高：锂空