《工业分析 Industrial Analysis》课件——煤中全硫的测定（双语）.pptxVIP

项目五:煤质分析

任务三：煤的元素分析;Scenario5:Qualityanalysisofcoals

TaskThree:Elementalanalysisofcoal;1、硫的存在形式;1、Theexistenceformofsulfur;高温燃烧中和法;Hightemperaturecombustionneutralizationmethod;3、硫的测定-艾氏卡法;3、Determinationofsulfur-Escarmethod;称取煤样(粒度应小干0.2mm)1g于30mL瓷坩埚中，加艾士卡试剂2g，混匀，置于高温炉中。在2h内从室温升到850℃，在850℃下加热2h，取出冷却到室温。用玻璃棒把熔块搅碎，熔块中应无残炭颗粒。;Weigh1gofcoalsample(particlesizeshouldbesmallanddry0.2mm)intoa30mLceramiccrucible,add2gofEscarreagent,mixwell,andplaceinahigh-temperaturefurnace.Raisethefurnacetemperaturefromroomtemperatureto850℃within2hours,heatat850℃for2hours,removetheporcelaincruciblefromthehigh-temperaturefurnace,andcooltoroomtemperature.Useaglassrodtocrushthemeltingblocksinthecrucible,andthereshouldbenoresidualcarbonparticlesinthemeltingblocks.;熔块;meltingblock;（3）艾士卡试剂的作用;（3）ThefunctionofEskareagent;（4）结果计算;（4）resultcalculation;4、硫的测定-高温燃烧中和法;4、Determinationofsulfur-Hightemperaturecombustionneutralizationmethod;高温燃烧-H2O2吸收中和法测定煤中全硫量的分析结果与艾士卡法相比，引起偏低的原因是：;Thereasonforthelowertotalsulfurcontentincoaldeterminedbythehigh-temperaturecombustionH2O2absorptionneutralizationmethodcomparedtotheEscarmethodis:;;;煤样在空气流中燃烧分解，煤中的硫生成SO2并被净化空气带到电解池中，立即被电解池中的I2氧化为H2SO4，溶液中的I2和I-浓度发生变化，指示电极的电位改变，从而启动电解，产生新的I2，使SO2全部被氧化，并使电解液重新回到平衡状态。根据电解所耗电量的积分及法拉第定律，可计算出试样中全硫的含量。;Thecoalsampleburnsanddecomposesintheairflow,andthesulfurinthecoalgeneratesSO2whichiscarriedbytheairtotheelectrolysiscell.ItisimmediatelyoxidizedtoH2SO4byI2intheelectrolysiscell.TheconcentrationofI2andI-intheelectrolytechanges,causingachangeintheindicatorelectrodepotential,whichinitiateselectrolysistogeneratenewI2,oxidizesallSO2,andreturnstheelectrolytetoanequilibriumstate.AccordingtotheelectricityconsumptionduringtheelectrolysisprocessandFaradayslaw,thetotalsulfurcontentinthesample