钾离子电池固态电池 Reaction and Capacity-Fading Mechanisms of Tin Nanoparticles in Potassium-Ion Batteries.pdfVIP

Article

pubs.acs.org/JPCC

ReactionandCapacity-FadingMechanismsofTinNanoparticlesin

Potassium-IonBatteries

QiannanWang,†,‡XinxinZhao,§,‡ChaolunNi,†,‡HeTian,†JixueLi,†ZeZhang,†ScottX.Mao,†

JiangweiWang,*,†andYunhuaXu*,§,∥

†CenterofElectronMicroscopyandStateKeyLaboratoryofSiliconMaterials,SchoolofMaterialsScienceandEngineering,Zhejiang

University,Hangzhou310027,China

§SchoolofMaterialsScienceandEngineeringandTianjinKeyLaboratoryofCompositeandFunctionalMaterials,TianjinUniversity,

Tianjin300072,China

∥CollaborativeInnovationCenterofChemicalScienceandEngineering(Tianjin),Tianjin300072,China

S

*SupportingInformation

ABSTRACT:Inthisarticle,wereportastudyoftheelectrochemicalperformanceanddegradationmechanismoftin(Sn)

nanoparticleanodesinpotassium-ionbatteries(KIBs).Ahighcapacityof197mAh/gwasfoundfortheSnnanoparticlesin

KIBs.Insitutransmissionelectronmicroscopycharacterizationrevealedatwo-steppotassiationmechanism:formationofaKSn

phaseafterfullpotassiationandreversiblenanoporeformationduringthecyclingofSnnanoparticles.However,significant

capacityfadingoccurredafterafewcycles,whichwascausedbytheseverepulverizationoftheSnnanoparticles.Thisworkoffers

afundamentalunderstandingofthereactionanddegradationmechanismsofalloying-typeanodesforKIBs,sheddinglightonthe

developmentofhigh-performanceKIBs.

1.INTRODUCTIONseveraldifferentalloys