现代有机质谱概论.pptxVIP

当代有机质谱概论杨松成仪器测试分析中心

OutlineIntroductionInstrumentofOMSTandemTechnologyMainApplicationMostNewAdvances

ModernOrganicMassSpectrometry(OMS)MolecularMassSpectrometry

OMSisabasicandhigh-technicalscienceInwhich,physics,electronicsandcomputersciencewereappliedtostudyphysicalandchemicalcharacteroforganicmolecules

MassSpectrometryhaditsorigininearlylastcenturyApplicationoforganicmassspectrometryforchemicalanalysisoccurredinearly1940s

Quantitativeanalysisofhydrocarbonmixtures(9)producedincatalyticcrackersMethodsrequiretimeFractionaldistillation,refractiveindex200hoursOrganicmassspectrometryonehourormore

Beginninginthe1950s,chemistshaveusedcommercialorganicmassspectrometerforidentificationandstructuralelucidationofawidevarietyoforganiccompounds

TheuseoftheMScombinedwiththeNMRIRandUVrevolutionizedthewayorganicchemistswentaboutidentifyinganddeterminingthestructureoforganicmolecules

OrganicMassSpectrometryDeterminemolecularweightElucidatestructureoforganicmoleculeIdentifyunknowncompoundsQuantifyknownmaterialsAccuracy,sensitiveandrapid

OMShasbeenapowerfulanalyticaltoolinmodernstructurechemistryandanalyticalchemistry

Beforethemiddleofthe1970sOMScouldonlyanalyzeorganicmoleculeswithmolecularweightbelow1000Da

1974PlasmaD