材料科学基础第九课：离子化合物结构规则.pptx

材料科学基础

FundamentalofMaterialsScience LessonnineSunXiao-DanTel:-mail:DepartmentofMaterialScienceandEngineeringTsinghuaUniversity.Beijing100084

3.6SomeRulesGoverningtheIonicCompoundsPauling’sthreerulesgoverningthestructureofioniccompounds.1.AnionCoordinationPolyhedronRuleEachcationissurroundedbyananionpolyhedron,thedistancebetweenanionandcationr0dependsonr+＋r-,whiletheCNdependsonr+/r-.

r0＞r+＋r－r0＝r+＋r－=re(equlibriumdistance)stableioniccompoundr0＜r+＋r－thereissomecovalentbondingstableu