核磁质谱图谱.pptxVIP

MassSpectrometryFundamentalsKeytopics:MassspectrometerIonization,Massanalyzers,MassspectrometersChargestateofproteinandpeptidesMALDI-TOFMS,ESIMSMassspectrumIsotopeandmass,IsotopeabundanceQualityparametersofmassspectrometerResolution,Massaccuracy,Sensitivity

IsotopicAbundance

(a+b)n

MassSpectrum

withSulfur=

MassSpectrum

withChlorine=

MassSpectrum

withBromine=

MassSpectra

ofAlkanesMorestablecarbocationswillbemoreabundant.=

MassSpectra

ofAlkenesResonance-stabilizedcationsfavored.=

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