(9页PPT)封闭式碳硼烷及Wade规则.pptVIP

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  • 2026-05-18 发布于广东
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6.1.3BorohydrideanionsBnHn2-andcarboranes?BnH(n+n?+m)withcloso-structuresandtheWade’sruleBnHn2-(closo):B4H42-(tetrahedral)B6H62-(octahedral)B8H82-(dodecahedral)B12H122-(icosahedral)Electron-deficientmulti-centerbondsc)NVEforthecageframeworkis(2n+2)a)NVEforthewholemoleculeis(4n+2).b)NVEfortheB-Hbondsis2n.polyhedrawithnvertices“Closo”series-formulaBnHn2-TotalvalenceelectronsNVE=3n(B)+n(H)+2(negativecharge)=4n+2EachBHbonduses2electrons.Hencetheskeletal(framework)valenceelectrons(NFE=4n+2-2n=

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