(99页PPT)σ配体与π成键.ppt

Problem:ThemetalloceneCp2NireactswithNi(CO)3toaffordabinuclearplex:Cp2Ni+Ni(CO)4?[CpNiCO]2+2CO

PleasederivetheNi-Nibondorderandstructureofthisplex!(Cp=cyclopentadienyl)1)VE=g=2x10(Ni:3d84s2)+2x5(Cp)+2x2(CO)=34b=(2x18-34)/2

文档评论(0)

1亿VIP精品文档

相关文档