（共10页PPT）金属金属键与金属团簇结构B.pptVIP

Examples:VE=g=4x9(Ir:5d76s2)+12x2(CO)=60b=(18n-g)/2=(18x4-60)/2=6Why?Ir(CO)3VE=9+3x2=15VAO(Ir)=9i.e.,(n-1)d(5)+ns(1)+np(3)?Beinglackof3VEtofulfillthe18erule!(Ir:5d76s2)?Tofulfillthe18erule!theIrinIr(CO)3hastoformthreecovalentM-MbondswithotherMcenters.InIr4(CO)12,eachIradoptsd2sp3hybridizationalongwiththreeVE’s/HO’sbeingusedtoformthreeM-Mbonds,aswellasthreeunhybridised5dAO’sdoublyoccupied.Examples:VE=g=4x9(Co:3d74s2