（共15页PPT）杂化轨道的夹角及其性质.pptVIP

3.Theanglebetweentwohybridorbitals1)spnhybridizationwhere?piisNotetheanglebetweenthetwovectors?piand?pjistheangleqijbetweenthetwohybridorbitals?hiand?hj,i.e.,Let’sdefine

Equivalenthybridization.e.g.,CH4Non-equivalenthybridization.e.g.,CHCl3,CH3ClNormalizationandorthogonalitysp:?=0.5?cos?=-1??=180.0?sp2:?=1/3?cos?=?0.5??=120.0?

Equivalenthybridization

OtherexamplesPH3,PF3,NF3,Non-equivalenthybridizationtwoN-Hbonds

Ford-s-phybridization,theanglesbetweentwohybridorbitalscanbecalculat